Baseline correction

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Jamal
Newbie
Posts: 4
Joined: Tue Dec 12, 2023 5:00 am

Baseline correction

Post by Jamal »

Hi everyone,

After a bacgkround subtraction (empty capillary measurement), I still have a huge baseline which runs diagonally from upper left to lower right corner. Then I applied the ES basecorr function which gave me below baseline. Is there is a better option to remove the baseline?

Thank you in advance!

PS. I tried all polynomial orders from 1 to 6, this is 5th order.

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YQ067_Baseline_correction_test.jpg
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katarkon
Local Expert
Posts: 193
Joined: Mon Jan 12, 2015 4:01 am

Re: Baseline correction

Post by katarkon »

I think the better way in Your case is recording and substracting of the baseline because it has the intensity an aorders larger then the signal.

Jamal
Newbie
Posts: 4
Joined: Tue Dec 12, 2023 5:00 am

Re: Baseline correction

Post by Jamal »

As I said in the post, I did measure an empty capilarry as background and subtracted it. So the red spectrum is after background subtraction. The yellow one is after polynomial baseline correction.

Stefan Stoll
EasySpin Creator
Posts: 1108
Joined: Mon Jul 21, 2014 10:11 pm
Location: University of Washington

Re: Baseline correction

Post by Stefan Stoll »

With 6.0.0-dev.x, you can specify the region to include in the baseline fit. in your case, I would exclude the regions 100-200 and 300-400 mT. That should give you a better baseline.

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