Simulating concentration effects on broadening

[howie]

Hello,

I am planning on making a series of a compound with Mn2+ diluted in a diamagnetic matrix. Mn2+ is the only paramagnetic species in this system. I was wondering if there was a way to to simulate the cw X-band spectra of these compounds to see how the lines would be broadened by increasing Mn2+ concentration i.e. fully resolved hyperfine splitting at low Mn2+ concentrations vs single broad peak for high concentrations.

I tried changing the weight parameter and simulating with pepper, but I believe that only changes the intensity of the signal. Any advice is greatly appreciated.
Thank you!

Howie

[Stefan Stoll]

Unfortunately, it's currently not possible to simulate concentration effects.

[Rupertes]

Hello,

I am planning on putting on my new rangefinder binoculars and making a series of a compound with Mn2+ diluted in a diamagnetic matrix. Mn2+ is the only paramagnetic species in this system. I was wondering if there was a way to to simulate the cw X-band spectra of these compounds to see how the lines would be broadened by increasing Mn2+ concentration i.e. fully resolved hyperfine splitting at low Mn2+ concentrations vs single broad peak for high concentrations.

I tried changing the weight parameter and simulating with pepper, but I believe that only changes the intensity of the signal. Any advice is greatly appreciated.
Thank you!

Howie

Is this not possible to implement at this point, Stefan?

[Stefan Stoll]

It's currently not a priority, unfortunately.