Search found 2 matches
- Thu Aug 19, 2021 6:51 pm
- Forum: General forum
- Topic: Simulating "Forbidden" Half-Field Transitions with Dipolar Interactions
- Replies: 3
- Views: 3788
Re: Simulating "Forbidden" Half-Field Transitions with Dipolar Interactions
This is very helpful. But how does easyspin then produce the half-field response? I would assume easyspin must transform the Hamiltonian and put it into a rotating reference frame to make an EPR signal possible. Is that true? If so, how does it eliminate the time dependence of the four terms (C,D,E,...
- Wed Aug 18, 2021 8:56 am
- Forum: General forum
- Topic: Simulating "Forbidden" Half-Field Transitions with Dipolar Interactions
- Replies: 3
- Views: 3788
Simulating "Forbidden" Half-Field Transitions with Dipolar Interactions
I am struggling to figure out how easyspin gives rise to the "forbidden" half-field transition with the introduction of a dipolar or zero-field splitting interaction between electrons. Terms A and B of the dipolar alphabet work with the rotating wave approximation and all time dependence i...