Search found 2 matches

by EliasFrantz
Thu Aug 19, 2021 6:51 pm
Forum: General forum
Topic: Simulating "Forbidden" Half-Field Transitions with Dipolar Interactions
Replies: 3
Views: 3339

Re: Simulating "Forbidden" Half-Field Transitions with Dipolar Interactions

This is very helpful. But how does easyspin then produce the half-field response? I would assume easyspin must transform the Hamiltonian and put it into a rotating reference frame to make an EPR signal possible. Is that true? If so, how does it eliminate the time dependence of the four terms (C,D,E,...
by EliasFrantz
Wed Aug 18, 2021 8:56 am
Forum: General forum
Topic: Simulating "Forbidden" Half-Field Transitions with Dipolar Interactions
Replies: 3
Views: 3339

Simulating "Forbidden" Half-Field Transitions with Dipolar Interactions

I am struggling to figure out how easyspin gives rise to the "forbidden" half-field transition with the introduction of a dipolar or zero-field splitting interaction between electrons. Terms A and B of the dipolar alphabet work with the rotating wave approximation and all time dependence i...