EasySpin forum

I collected data for an irradiated suspension of struvite in aqueous DMPO solution and found that it generates OH, OOH, H, and singlet oxygen. I was able to fit it by using a linear combination of "garlic" simulations for the DMPO adducts of those 4 species. Overall, I am satisfied with my...

I recently collected experimental data of several types of DMPO adducts and oxidation products. I was able to sum several simulations together and match all of the features, but the features line up better with my experimental data at higher field values. Do I need to try a different g-value, or is ...

Thank you for taking the time to write this code. I am confused as to how you came up with the parameters for the g-value and the hyperfine splittings. I'm guessing the two sets of two equivalent hydrogen nuclei come from the other positions on the ring? I was hoping to identify specific reactive ox...

I collected an EPR spectrum of photolyzed struvite in the presence of DMPO in water. I expect it to mainly generate reactive oxygen species. I then simulated EPR spectra for several DMPO adducts and oxidation products using the literature hyperfine splitting values from Buettner's 1987 Free Radical ...

I collected an EPR spectrum of DMPO-OH (produced by photolyzing H2O2 in water with DMPO) to practice fitting in Easyspin. I adapted the code from the fitting example on the YouTube channel and used the literature g-value of 2.0062, allowing for a variation of 0.004. I was satisfied with the fit, but...